Strong-coupling expansions for the anharmonic Holstein model and for the Holstein-Hubbard model.

A strong-coupling expansion is applied to the anharmonic Holstein model and to the Holstein-Hubbard model through fourth order in the hopping matrix element. Mean-field theory is then employed to determine transition temperatures of the effective (pseudospin) Hamiltonian. We find that anharmonic effects are not easily mimicked by an on-site Coulomb repulsion, and that anharmonicity strongly favors superconductivity relative to charge-density-wave order. Surprisingly, the phase diagram is strongly modified by relatively small values of the anharmonicity. Typeset using REVTEX c © 1996 by the authors. Reproduction of this article by any means is permitted for non-commercial purposes.